Cationic silyldiazenido complexes of the Fe(diphosphine)2(N2) platform: structural and electronic models for an elusive first intermediate in N2 fixation
The first cationic Fe silyldiazenido complexes, [Fe(PP)2(NN-SiMe3)]+[BArF4]- (PP = dmpe/depe), have been synthesised and thoroughly characterised. Computational studies show the compounds to be useful structural and electronic surrogates for the more elusive [Fe(PP)2(NN-H)]+, which are postulated in...
| Автори: | , , , , , |
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| Формат: | Journal article |
| Мова: | English |
| Опубліковано: |
Royal Society of Chemistry
2017
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