New and versatile routes to zirconium imido dichloride compounds.

Reactions of zirconium dialkyl- or bis(amido)-dichloride complexes "[Zr(CH2SiMe3)2Cl2(Et2O)2]" or [Zr(NMe2)2Cl2(THF)2] with primary alkyl and aryl amines are described. Reaction of "[Zr(CH2SiMe3)2Cl2(Et2O)2]" with RNH2 in THF afforded dimeric [Zr2(mu-NR)2Cl4(THF)4](R=2,6-C6H3iPr2...

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Váldodahkkit: Dubberley, SR, Evans, S, Boyd, C, Mountford, P
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 2005