New and versatile routes to zirconium imido dichloride compounds.
Reactions of zirconium dialkyl- or bis(amido)-dichloride complexes "[Zr(CH2SiMe3)2Cl2(Et2O)2]" or [Zr(NMe2)2Cl2(THF)2] with primary alkyl and aryl amines are described. Reaction of "[Zr(CH2SiMe3)2Cl2(Et2O)2]" with RNH2 in THF afforded dimeric [Zr2(mu-NR)2Cl4(THF)4](R=2,6-C6H3iPr2...
| Hlavní autoři: | , , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
2005
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