Electronic structure of strained silicon- and sulfur-bridged [1]ferrocenophanes and an analogous dicarbon-bridged [2]ferrocenophane: An investigation by photoelectron spectroscopy and density-functional theory
He I and He II photoelectron (PE) spectra of [Fe(η-C2H4)2SiMe2] (1), [Fe(η-C5H3Me)2SiMe2] (2), [Fe(η-C5H4)(η-C5Me 4)SiMe2] (3), [Fe(η-C5Me4)2SiMe2] (4), [Fe(η-C5H4)2C2H4] (5), and [Fe-(η-C5H4)2S] (6) have been measured and assigned. The d bands of 1-5 show less structure than that of ferrocene, cons...
| Main Authors: | , , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1998
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