Catalytic intramolecular ketone hydroacylation: enantioselective synthesis of phthalides.
Controlling carbonyl groups: Identification of the correct ligand/counterion combination was essential to allow the efficient and selective rhodium-catalyzed conversion of a series of ketobenzaldehydes into the corresponding phthalides using the title reaction (see scheme; cod=cycloocta-l,5-diene)....
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Format: | Journal article |
Sprog: | English |
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2010
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