Synthesis and Characterization of Group 4 Permethylpentalene Dichloride Complexes
We report the high-yield syntheses of the (η8-Pn*) MCl2 complexes (η8-Pn* = C8Me 6; M = Ti, Zr, Hf), utilizing the cis-(SnMe3) 2Pn* or cis-Li2Pn*(TMEDA)x synthons. Stereoselective synthesis of the appropriate Pn* precursor [cis-Li2Pn* and cis-(SnMe3)2Pn*] can be achieved by the appropriate choice of...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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