Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3.
Chromium and ruthenium complexes of the chelating phosphine borane H(3)B.dppm are reported. Addition of H(3)B.dppm to [Cr(CO)(4)(nbd)](nbd = norbornadiene) affords [Cr(CO)(4)(eta1-H(3)B.dppm)] in which the borane is linked to the metal through a single B-H-Cr interaction. Addition of H(3)B.dppm to [...
| Main Authors: | , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2004
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