Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3.

Transition metal complexes of the chelating phosphine borane ligand Ph2PCH2Ph2P.BH3.

Chromium and ruthenium complexes of the chelating phosphine borane H(3)B.dppm are reported. Addition of H(3)B.dppm to [Cr(CO)(4)(nbd)](nbd = norbornadiene) affords [Cr(CO)(4)(eta1-H(3)B.dppm)] in which the borane is linked to the metal through a single B-H-Cr interaction. Addition of H(3)B.dppm to [...

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Bibliographic Details
Main Authors:	Merle, N, Koicok-Köhn, G, Mahon, M, Frost, C, Ruggerio, G, Weller, A, Willis, M
Format:	Journal article
Language:	English
Published:	2004

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