Mechanism of hydrogen activation by [NiFe] hydrogenases
The active site of [NiFe] hydrogenases contains a strictly conserved arginine that suspends a guanidine nitrogen atom <4.5 Å above the nickel and iron atoms. The guanidine headgroup interacts with the side chains of two conserved aspartic acid residues to complete an outer-shell canopy that h...
| Glavni autori: | , , , , , , , |
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| Format: | Journal article |
| Izdano: |
Nature Publishing Group
2015
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