The directed dihydroxylation of allylic alcohols
The preparation and dihydroxylation of a series of polyenes and cyclic allylic alcohols using the TMEDA/osmium tetroxide mixture is reported. Remarkably, these reagents lead to high levels of regiochemical and stereochemical control as the oxidant hydrogen-bonds to the allylic alcohol group. A mecha...
| Asıl Yazarlar: | , , , |
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| Materyal Türü: | Journal article |
| Baskı/Yayın Bilgisi: |
1997
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