Compositional inhomogeneity and tuneable thermal expansion in mixed-metal ZIF-8 analogues
We study the structural and thermomechanical effects of cation substitution in the compositional family of metal–organic frameworks Zn1−xCdx(mIm)2 (HmIm = 2-methylimidazole). We find complete miscibility for all compositions x, with evidence of inhomogeneous distributions of Cd and Zn that in turn a...
| Main Authors: | , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
Royal Society of Chemistry
2018
|