LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25:topochemically reduced, mixed valence Rh(I)/Rh(III) Oxides

Topochemical reduction of the n = 1 Ruddlesden-Popper phases LaSrCo0.5Rh0.5O4 and LaSrNi0.5Rh0.5O4 with Zr yields LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25, respectively. Magnetization and XPS data reveal that while the rhodium centers in LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25 have an average...

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Principais autores: Xu, Z, Palgrave, RG, Hayward, MA
Formato: Journal article
Idioma:English
Publicado em: American Chemical Society 2020