LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25:topochemically reduced, mixed valence Rh(I)/Rh(III) Oxides
Topochemical reduction of the n = 1 Ruddlesden-Popper phases LaSrCo0.5Rh0.5O4 and LaSrNi0.5Rh0.5O4 with Zr yields LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25, respectively. Magnetization and XPS data reveal that while the rhodium centers in LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25 have an average...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2020
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