LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25:topochemically reduced, mixed valence Rh(I)/Rh(III) Oxides

LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25:topochemically reduced, mixed valence Rh(I)/Rh(III) Oxides

Topochemical reduction of the n = 1 Ruddlesden-Popper phases LaSrCo0.5Rh0.5O4 and LaSrNi0.5Rh0.5O4 with Zr yields LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25, respectively. Magnetization and XPS data reveal that while the rhodium centers in LaSrCo0.5Rh0.5O3.25 and LaSrNi0.5Rh0.5O3.25 have an average...

書誌詳細
主要な著者:	Xu, Z, Palgrave, RG, Hayward, MA
フォーマット:	Journal article
言語:	English
出版事項:	American Chemical Society 2020

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