Redox systems obeying Marcus-Hush-Chidsey electrode kinetics do not obey the Randles-Sevcik equation for linear sweep voltammetry
The cyclic voltammetry of the reaction of a solution-phase species at a macroelectrode under semi-infinite diffusion is simulated assuming irreversible electrode kinetics within the Marcus-Hush-Chidsey model. The resulting peak currents are shown to deviate from the square root dependence on voltage...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2012
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