Solid and solution state structures of a reversible molecular oxygen-carrying molybdenum porphyrin dioxygen complex
The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion...
詳細記述
書誌詳細
主要な著者: |
Fujihara, T,
Rees, N,
Umakoshi, K,
Tachibana, J,
Sasaki, Y,
McFarlane, W,
Imamura, T |
フォーマット: | Journal article
|
言語: | English |
出版事項: |
2000
|