Solid and solution state structures of a reversible molecular oxygen-carrying molybdenum porphyrin dioxygen complex

Solid and solution state structures of a reversible molecular oxygen-carrying molybdenum porphyrin dioxygen complex

The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion...

Полное описание

Библиографические подробности
Главные авторы:	Fujihara, T, Rees, N, Umakoshi, K, Tachibana, J, Sasaki, Y, McFarlane, W, Imamura, T
Формат:	Journal article
Язык:	English
Опубликовано:	2000

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