Ordered B-site vacancies in an ABX3 formate perovskite
We report the synthesis and structural characterization of the ABX3 perovskite frameworks [C(NH2)3]Mn1–x2+(Fe2x/33+,□x/3)(HCOO)3 (□ = B-site vacancy). For large x, the vacancies order, lowering the crystal symmetry. This system establishes B-site vacancies as a new type of defect in formate perovski...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
American Chemical Society
2019
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