Synthesis and imido-group exchange reactions of tert-butylimidotitanium complexes
Treatment of TiCl4 with ButNH2 (6 equivalents) followed by addition of bpy (2 equivalents, 4-/er/-butylpyridine) or pyridine (py) (2 or 4 equivalents) afforded the five- or six-co-ordinate /erf-butylimido complexes [ri(NBut)Cl2(bpy)2] or [Ti(NBut)Cl2(py)n] ( = 2 or 3) respectively in good yields. Re...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1997
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