Synthesis and imido-group exchange reactions of tert-butylimidotitanium complexes

Treatment of TiCl4 with ButNH2 (6 equivalents) followed by addition of bpy (2 equivalents, 4-/er/-butylpyridine) or pyridine (py) (2 or 4 equivalents) afforded the five- or six-co-ordinate /erf-butylimido complexes [ri(NBut)Cl2(bpy)2] or [Ti(NBut)Cl2(py)n] ( = 2 or 3) respectively in good yields. Re...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Blake, A, Collier, P, Dunn, S, Li, W, Mountford, P, Shishkin, O
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 1997