A homologous series of first-row transition-metal complexes of 2,2'-bipyridine and their ligand radical derivatives: trends in structure, magnetism, and bonding.
The organometallic first-row transition-metal complexes [M(2,2'-bipy)(mes)2] (M = Cr (1), Mn (2), Co (4), Ni (5); 2,2'-bipy = 2,2'-bipyridine; mes = 2,4,6-Me3C6H2) were reacted with potassium and a suitable alkali-metal sequestering agent to yield salts of the anionic species [M(2,2&#...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2012
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