Enantio- and diastereoselective catalytic alkylation reactions with aziridines.

Enantio- and diastereoselective catalytic alkylation reactions with aziridines.

The first asymmetric phase transfer catalyzed alkylation reaction of a range of carbon acids with N-sulfonyl aziridines is reported. When 10 mol % of a cinchona derived quaternary ammonium salt was employed as the catalyst under mildly basic conditions, N-o-(trifluoromethane)benzenesulfonyl aziridin...

Descripció completa

Dades bibliogràfiques
Autors principals:	Moss, T, Fenwick, DR, Dixon, D
Format:	Journal article
Idioma:	English
Publicat:	2008

Ítems similars

Catalytic enantio- and diastereoselective alkylations with cyclic sulfamidates.
per: Moss, T, et al.
Publicat: (2010)

Direct catalytic enantio- and diastereoselective Mannich reaction of isocyanoacetates and ketimines.
per: Ortín, I, et al.
Publicat: (2014)

Catalytic enantio- and diastereoselective Mannich reaction of α-substituted isocyanoacetates and ketimines.
per: de la Campa, R, et al.
Publicat: (2016)

Catalytic enantio- and diastereoselective mannich addition of TosMIC to ketimines
per: Franchino, A, et al.
Publicat: (2018)

Efficient base catalyzed alkylation reactions with aziridine electrophiles.
per: Moss, T, et al.
Publicat: (2008)

Bifunctional iminophosphorane superbases: Potent organocatalysts for enantio- and diastereoselective Michael addition reactions
per: Farley, A, et al.
Publicat: (2018)

Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades.
per: Li, M, et al.
Publicat: (2013)

Alkylative Aziridine Ring-Opening Reactions
per: Jieun Choi, et al.
Publicat: (2021-03-01)

Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones
per: Pier Giorgio Cozzi, et al.
Publicat: (2011-06-01)

Enantio- and diastereoselective Suzuki-Miyaura coupling with racemic bicycles
per: Goetzke, F, et al.
Publicat: (2019)

Highly enantio- and diastereoselective reactions of γ-substituted butenolides through direct vinylogous conjugate additions
per: Zhang, Wen, et al.
Publicat: (2013)

A new family of cinchona-derived amino phosphine precatalysts: application to the highly enantio- and diastereoselective silver-catalyzed isocyanoacetate aldol reaction.
per: Sladojevich, F, et al.
Publicat: (2011)

Computational ligand design in enantio- and diastereoselective ynamide [5+2] cycloisomerization.
per: Straker, R, et al.
Publicat: (2016)

Computational ligand design in enantio- and diastereoselective ynamide [5+2] cycloisomerization
per: R. N. Straker, et al.
Publicat: (2016-01-01)

Rhodium-catalysed enantio- and diastereoselective C(sp2)-C(sp3) cross-coupling reactions
per: Goetzke, FW
Publicat: (2021)

A new family of cinchona-derived bifunctional asymmetric phase-transfer catalysts: application to the enantio- and diastereoselective nitro-Mannich reaction of amidosulfones.
per: Johnson, K, et al.
Publicat: (2012)

Enantio- and diastereoselective Michael additions of C-succinimidyl esters to nitro olefins using cinchonine-derived bifunctional organocatalysts
per: Jakubec, P, et al.
Publicat: (2011)

Direct enantio- and diastereoselective Mannich reactions of malonate and beta-keto esters with N-Boc and N-Cbz aldimines catalysed by a bifunctional cinchonine derivative.
per: Tillman, A, et al.
Publicat: (2006)

Nickel-Catalyzed Enantio- and Diastereoselective Synthesis of Fluorine-Containing Vicinal Stereogenic Centers
per: Uttam Dhawa, et al.
Publicat: (2024-08-01)

Organocatalytic enantio- and diastereoselective cycloetherification via dynamic kinetic resolution of chiral cyanohydrins
per: Naoki Yoneda, et al.
Publicat: (2017-11-01)

Combining cycloisomerization with trienamine catalysis: a regiochemically flexible enantio- and diastereoselective synthesis of hexahydroindoles
per: Chintalapudi, V, et al.
Publicat: (2015)

Novel Chiral Thiourea Derived from Hydroquinine and l‑Phenylglycinol: An Effective Catalyst for Enantio- and Diastereoselective Aza-Henry Reaction
per: Jingdong Wang, et al.
Publicat: (2021-02-01)

Diastereoselectivity in the alkylations of bicyclic piperidinones
per: Mills, C, et al.
Publicat: (1998)

On the diastereoselectivity of alkylations of bicyclic lactams
per: Bailey, J, et al.
Publicat: (2000)

Organocatalytic asymmetric Mannich reactions of 5H-oxazol-4-ones : highly enantio- and diastereoselective synthesis of chiral α-alkylisoserine derivatives
per: Han, Zhiqiang, et al.
Publicat: (2014)

On the origins of diastereoselectivity in the alkylation of diketopiperazine enolates
per: Bull, S, et al.
Publicat: (2007)

Coupling of 1-alkyl-2-(bromomethyl)aziridines with heteroatom-centered nucleophiles towards 2-[(heteroatom)methyl]aziridines
per: Matthias D’hooghe, et al.
Publicat: (2007-08-01)

Enantio- and diastereoselective synthesis of chromeno[4,3-b]pyrrole derivatives bearing tetrasubstituted chirality centers through carbene catalyzed cascade reactions
per: Li, Tingting, et al.
Publicat: (2020)

Catalytic asymmetric aziridination of aryl imines
per: Peter Wipf, et al.
Publicat: (2007-04-01)

Highly chemo-, enantio-, and diastereoselective [4 + 2] cycloaddition of 5H-thiazol-4-ones with N-itaconimides
per: Shuai Qiu, et al.
Publicat: (2016-11-01)

Molybdenum and tungsen alkylidene species for catalytic Enantio-, Z-, and E-selective olefin metathesis reactions
per: Marinescu, Smaranda Constanţa
Publicat: (2011)

Reactivity of 1-alkyl-2-(bromomethyl)aziridines towards n-butyllithium
per: Matthias D’hooghe, et al.
Publicat: (2007-08-01)

Catalytic asymmetric alkylation reactions for the construction of protected ethylene-amino and propylene-amino motifs attached to quaternary stereocentres.
per: Moss, T, et al.
Publicat: (2013)

Enantioenriched a-substituted aldehydes via diastereoselective enamine alkylation
per: Kaka, N, et al.
Publicat: (2007)

Synthesis of chiral 1-(2-aminoalkyl)aziridines via the self-opening reaction of aziridine
per: Adam M. Pieczonka, et al.
Publicat: (2016-09-01)

Organolithium-induced alkylative ring opening of aziridines: synthesis of unsaturated amino alcohols and ethers.
per: Hodgson, D, et al.
Publicat: (2006)

Spiro-fused carbohydrate oxazoline ligands: Synthesis and application as enantio-discrimination agents in asymmetric allylic alkylation
per: Jochen Kraft, et al.
Publicat: (2016-01-01)

CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines
per: Wang, Haoxuan, et al.
Publicat: (2018)

Substituted aziridines by lithiation-electrophile trapping of terminal aziridines.
per: Hodgson, D, et al.
Publicat: (2005)

Direct catalytic diastereoselective Mannich reactions: the synthesis of protected alpha-hydroxy-beta-aminoketones
per: Stainforth, N, et al.
Publicat: (2009)