Solution phase structures of enantiopure and racemic lithium N-benzyl-N-(alpha-methylbenzyl)amide in THF: low temperature Li-6 and N-15 NMR spectroscopic studies
The antipodes of lithium N-benzyl-N-(α-methylbenzyl)amide are highly efficient enantiopure ammonia equivalents for the asymmetric synthesis of β-amino acid derivatives via conjugate addition to α,β- unsaturated esters. 6Li and 15N NMR spectroscopic studies of doubly labelled 6lithium (S)-15N-benzyl-...
Main Authors: | , , , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
2013
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