New reactivity and selectivity in rhodium-catalysed hydroacylation

New reactivity and selectivity in rhodium-catalysed hydroacylation

<p>This thesis documents the development of two new rhodium(I)-catalysed methodologies. The first shows the use of 1,4-dicarbonyl systems in hydroacylation for the preparation of synthetically valuable alpha-N-amido ketones. The second method is a dynamic kinetic resolution process for the syn...

Disgrifiad llawn

Manylion Llyfryddiaeth
Prif Awdur:	Pal, R
Awduron Eraill:	Willis, M
Fformat:	Traethawd Ymchwil
Iaith:	English
Cyhoeddwyd:	2020
Pynciau:	Metal-catalysis Organic synthesis

Eitemau Tebyg

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
gan: Poingdestre, SJ
Cyhoeddwyd: (2012)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
gan: Ylioja, P
Cyhoeddwyd: (2011)

New applications of rhodium-catalysed hydroacylation
gan: Iwumene, NUN
Cyhoeddwyd: (2022)

Tandem catalytic processes involving Rhodium-catalysed intermolecular hydroacylation
gan: Lenden, P
Cyhoeddwyd: (2011)

Applications of rhodium-catalysed hydroacylation in heterocycle synthesis
gan: Majhail, M
Cyhoeddwyd: (2016)

Mechanistic studies of rhodium-catalysed intermolecular hydroacylation
gan: Barwick-Silk, J
Cyhoeddwyd: (2018)

Rhodium-catalysed linear-selective alkyne hydroacylation.
gan: Poingdestre, S, et al.
Cyhoeddwyd: (2012)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
gan: Pawley, R
Cyhoeddwyd: (2012)

Rhodium(I) catalysis for intermolecular alkyne hydroacylation and desymmetrisation
gan: Moseley, D
Cyhoeddwyd: (2022)

Ketone synthesis via rhodium-catalyzed traceless chelation-controlled hydroacylation reactions
gan: Gao, M
Cyhoeddwyd: (2018)

Exploring small bite-angle PNP and PCP ligands for the rhodium-catalysed intermolecular hydroacylation of b-s-substituted aldehydes with alkenes and alkynes
gan: Pernik, I
Cyhoeddwyd: (2014)

Asymmetric rhodium catalysed arylation: from ligand design to application
gan: Hell, AML
Cyhoeddwyd: (2020)

Rhodium-catalysed hydroacylation or reductive aldol reactions: a ligand dependent switch of reactivity.
gan: Osborne, J, et al.
Cyhoeddwyd: (2008)

Investigating rhodium-catalysed hydroacylation and carbon-carbon bond activation
gan: Coxon, T
Cyhoeddwyd: (2017)

Studies toward the application and development of rhodium-catalysed hydroacylation reactions
gan: Neuhaus, J
Cyhoeddwyd: (2016)

The understanding and development of rhodium-catalysed asymmetric cross-coupling reactions
gan: Van Dijk, L
Cyhoeddwyd: (2021)

Cp*Rh(III)-catalysed enantioselective C(sp3)–H functionalisation
gan: Xu, X
Cyhoeddwyd: (2024)

Exploiting rhodium-catalysed ynamide hydroacylation as a platform for divergent heterocycle synthesis
gan: Straker, R, et al.
Cyhoeddwyd: (2017)

Palladium-catalysed cyclisations of bromoenynamides in the synthesis and applications of amidodienes
gan: Greenaway, R
Cyhoeddwyd: (2013)

Rhodium-catalysed C(sp2)–C(sp2) bond formation via C–H/C–F activation
gan: Tian, Panpan, et al.
Cyhoeddwyd: (2018)

Palladium-catalysed enolate arylation in the synthesis of isoquinolines
gan: Gatland, A, et al.
Cyhoeddwyd: (2014)

Palladium- and copper-catalysed heterocycle synthesis
gan: Ball, C
Cyhoeddwyd: (2014)

Rhodium-catalysed intermolecular alkyne hydroacylation: the enantioselective synthesis of α- and β-substituted ketones by kinetic resolution.
gan: González-Rodríguez, C, et al.
Cyhoeddwyd: (2010)

Replacing dichloroethane as a solvent for rhodium-catalysed intermolecular alkyne hydroacylation reactions: the utility of propylene carbonate
gan: Lenden, P, et al.
Cyhoeddwyd: (2011)

Rhodium (I) catalyzed intermolecular hydroacylation.
gan: Sapmaz, S, et al.
Cyhoeddwyd: (2001)

Cyclisation cascades via reactive iminium intermediates
gan: Gregory, AW
Cyhoeddwyd: (2014)

SYNERGISMS BETWEEN METAL AND PHOTOREDOX CATALYSIS: DECONVOLUTING COMPLEX SYSTEMS
gan: Alessandra A. G. Fernandes, et al.
Cyhoeddwyd: (2020-08-01)

Gold film-catalysed benzannulation by Microwave-Assisted, Continuous Flow Organic Synthesis (MACOS)
gan: Gjergji Shore, et al.
Cyhoeddwyd: (2009-07-01)

Special Issue: “Advances in Homogeneous Catalysis”
gan: Joaquín García-Álvarez
Cyhoeddwyd: (2020-03-01)

Novel palladium-catalysed routes to aromatic heterocycles
gan: Pilgrim, B, et al.
Cyhoeddwyd: (2013)

Rhodium-catalyzed enantioselective intermolecular hydroacylation reactions
gan: Gonzalez-Rodriguez, C, et al.
Cyhoeddwyd: (2011)

Palladium-catalysed heterocycle synthesis
gan: Sadig, JER
Cyhoeddwyd: (2012)

Synthesis of mono- and bicyclic azacycles via palladium- and ruthenium-catalysed enynamide cycloisomerisation
gan: Walker, P, et al.
Cyhoeddwyd: (2014)

Transition metal catalysed C-C bond formation via C-H functionalisation
gan: Truscott, FR
Cyhoeddwyd: (2012)

An enamine controlling group for rhodium-catalyzed intermolecular hydroacylation
gan: Straker, R, et al.
Cyhoeddwyd: (2018)

Copper-catalyzed radical trans-selective hydroboration of ynamides with N-heterocyclic carbene boranes
gan: Kefeng Wang, et al.
Cyhoeddwyd: (2022-09-01)

Highly Reactive Cyclic Monoaryl Iodoniums Tuned as Carbene Generators Couple with Nucleophiles under Metal-Free Conditions
gan: Haiwen Wang, et al.
Cyhoeddwyd: (2020-07-01)

Recent advances in metal-catalysed oxidation reactions
gan: Aleena Raju, et al.
Cyhoeddwyd: (2025-01-01)

Bifunctional iminophosphorane superbase catalysed enantioselective intramolecular michael reactions
gan: Su, G
Cyhoeddwyd: (2022)

Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans
gan: Subrahmanya Ishwar Bhat, et al.
Cyhoeddwyd: (2025-01-01)