Allylic alcohols and amines by carbenoid eliminative cross-coupling using epoxides or aziridines
α-Lithiated terminal epoxides and N-(tert-butylsulfonyl)aziridines undergo eliminative cross-coupling with α-lithio ethers, to give convergent access to allylic alcohols and allylic amines, respectively. The process can be considered as proceeding by selective strain-relieving attack (ring-opening)...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
| Published: |
Beilstein-Institut
2021
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