Extending the chain: synthetic, structural, and reaction chemistry of a BN allenylidene analogue.
α versus γ: [CpFe(CO)(PCy3)(BNCMes 2)]+, synthesized by halide abstraction, represents the first example of a BN allenylidene analogue, and features an unsaturated MBNC π system. Although DFT calculations show significant LUMO amplitude at the γ (carbon) position, primary reactivity towards nucleoph...
| Autori principali: | , , , , , , |
|---|---|
| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
2011
|