Osmium-catalyzed oxidative cyclization of dienes and their derivatives.

The development and application of novel methods for accomplishing the synthesis of heterocycles via osmium-catalyzed oxidative cyclization onto an alkene is described in this Perspective. Beginning with a fortuitous discovery, an extensive examination of the possible mechanism of cyclization has be...

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Váldodahkkit: Pilgrim, B, Donohoe, T
Materiálatiipa: Journal article
Giella:English
Almmustuhtton: 2013