Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl.

The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis...

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Bibliographic Details
Main Authors: Hill, L, Blackburn, O, Jones, M, Tropiano, M, Sørensen, T, Faulkner, S
Format: Journal article
Language:English
Published: 2013