Ternary self-assemblies in water: forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)3(dinicotinate)2Cl.
The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1 : 2 complex with α,α'-bis...
Main Authors: | Hill, L, Blackburn, O, Jones, M, Tropiano, M, Sørensen, T, Faulkner, S |
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Format: | Journal article |
Sprog: | English |
Udgivet: |
2013
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