Powder diffraction refinements of the structure of magnetite (Fe3O4) below the Verwey transition

Magnetite is a classic example of a mixed-valent transition metal oxide, in which electronic conductivity and ferromagnetism result from electron hopping between octahedrally coordinated Fe2+ and Fe3+ states. Below the 122 K Verwey transition, the conductivity falls by a factor of ∼100 and a complex...

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Bibliographic Details
Main Authors: Wright, J, Paul Attfield, J, Radaelli, P
Format: Journal article
Language:English
Published: 2001