PGSE diffusion studies on chelating phosphine complexes of ruthenium(II). Solvent dependence and ion pairing
PGSE 1H and 19F diffusion data, D values, and 1H,19F HOESY NMR spectra for a series of [RuCl(p-cymene)(BINAP)]X salts, 2a-f, have been recorded in CD2Cl2 (X = BF4- (2a), CF3 SO3- (2b), BArF- (2c), PF6- (2d), SbF6- (2e), Cl- (2f)). The solvent dependence of the D values for 2a-c in methanol, chlorofo...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2003
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