The [2,3] sigmatropic rearrangement of N-benzyl-O-allylhydroxylamines
The rearrangement of a range of N-benzyl-O-allylhydroxylamines to the corresponding N-allylhydroxylamines upon treatment with n-BuLi in THF, followed by reduction to the corresponding N-allylamines, is described. Mechanistic studies of the transformation are consistent with an intramolecular [2,3] s...
Main Authors: | , , , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
2002
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