The [2,3] sigmatropic rearrangement of N-benzyl-O-allylhydroxylamines

The rearrangement of a range of N-benzyl-O-allylhydroxylamines to the corresponding N-allylhydroxylamines upon treatment with n-BuLi in THF, followed by reduction to the corresponding N-allylamines, is described. Mechanistic studies of the transformation are consistent with an intramolecular [2,3] s...

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Autors principals: Davies, S, Fox, J, Jones, S, Price, A, Sanz, M, Sellers, T, Smith, A, Teixeira, F
Format: Journal article
Idioma:English
Publicat: 2002