The synthesis and characterisation of some Group 14 compounds containing the 2,4,6-(CF3)(3)C6H2, 2,6-(CF3)(2)C6H3 or 2,4-(CF3)(2)C6H3 ligands
New (aryl)2ECl2 and (aryl)ECl3 compounds [E = Si, Ge or Sn; aryl = 2,4,6-(CF3)3C6H 2 (Ar), 2,6-(CF3)2C6H3 (Ar′) and/or 2,4-(CF3)3C6H3 (Ar″)] were prepared by reactions of ECl4 with 2 equivalents of ArLi or of a Ar′Li/Ar″Li mixture. The latter gives predominantly the less sterically hindered product...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2003
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