Total synthesis of (−)-himalensine A
The first enantioselective synthesis of (-)-himalensine A has been achieved in 22 steps. The synthesis was enabled by a novel catalytic, enantioselective prototropic shift/furan Diels-Alder (IMDAF) cascade to construct the ACD tricyclic core. A reductive radical cyclization cascade was utilized to b...
Main Authors: | , , , , , , |
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Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2017
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