Imido-alkyne coupling in titanium complexes: New insights into the alkyne hydroamination reaction
Titanium imido complexes [Ti(NR)(N2ArN py)(L)] (N2ArNpy = MeC(2-C 5H4N)(CH2NAr)2, Ar = 4-C 6H4-Me or 3,5-C6H3Me2) have been prepared from the corresponding bis(amide) complexes [Ti(N 2ArNpy)-(NMe2)2]. The reaction chemistry of the imido ligand has been investigated with aryl acetylenes, affording th...
| Główni autorzy: | , , , , , |
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| Format: | Journal article |
| Język: | English |
| Wydane: |
2007
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