Can heterometallic 1-dimensional chains support current rectification?
To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectifica...
প্রধান লেখক: | , , |
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বিন্যাস: | Journal article |
ভাষা: | English |
প্রকাশিত: |
2013
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সংক্ষিপ্ত: | To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios. |
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