Can heterometallic 1-dimensional chains support current rectification?

To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectifica...

সম্পূর্ণ বিবরণ

গ্রন্থ-পঞ্জীর বিবরন
প্রধান লেখক: DeBrincat, D, Keers, O, McGrady, J
বিন্যাস: Journal article
ভাষা:English
প্রকাশিত: 2013
বিবরন
সংক্ষিপ্ত:To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectification ratios.