Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates
Alkylation studies on the enolate of N-methyl morpholinone 7 clearly reveal that the observed cis-selectivity is consistent with a chiral relay system operating to invert the stereochemical information of the auxiliary's C5 stereogenic centre.
| Main Authors: | , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
1998
|
| _version_ | 1826268035010265088 |
|---|---|
| author | Bull, S Davies, S Fox, D Sellers, T |
| author_facet | Bull, S Davies, S Fox, D Sellers, T |
| author_sort | Bull, S |
| collection | OXFORD |
| description | Alkylation studies on the enolate of N-methyl morpholinone 7 clearly reveal that the observed cis-selectivity is consistent with a chiral relay system operating to invert the stereochemical information of the auxiliary's C5 stereogenic centre. |
| first_indexed | 2024-03-06T21:03:25Z |
| format | Journal article |
| id | oxford-uuid:3ba1f17d-de26-4c70-9140-f8819d434a6e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-06T21:03:25Z |
| publishDate | 1998 |
| record_format | dspace |
| spelling | oxford-uuid:3ba1f17d-de26-4c70-9140-f8819d434a6e2022-03-26T14:08:48ZChiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolatesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:3ba1f17d-de26-4c70-9140-f8819d434a6eEnglishSymplectic Elements at Oxford1998Bull, SDavies, SFox, DSellers, TAlkylation studies on the enolate of N-methyl morpholinone 7 clearly reveal that the observed cis-selectivity is consistent with a chiral relay system operating to invert the stereochemical information of the auxiliary's C5 stereogenic centre. |
| spellingShingle | Bull, S Davies, S Fox, D Sellers, T Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates |
| title | Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates |
| title_full | Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates |
| title_fullStr | Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates |
| title_full_unstemmed | Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates |
| title_short | Chiral relay effects influence the facial selectivity of N-alkylated 5-phenylmorpholin-2-one enolates |
| title_sort | chiral relay effects influence the facial selectivity of n alkylated 5 phenylmorpholin 2 one enolates |
| work_keys_str_mv | AT bulls chiralrelayeffectsinfluencethefacialselectivityofnalkylated5phenylmorpholin2oneenolates AT daviess chiralrelayeffectsinfluencethefacialselectivityofnalkylated5phenylmorpholin2oneenolates AT foxd chiralrelayeffectsinfluencethefacialselectivityofnalkylated5phenylmorpholin2oneenolates AT sellerst chiralrelayeffectsinfluencethefacialselectivityofnalkylated5phenylmorpholin2oneenolates |