Filling vacancies in a Prussian blue analogue using mechanochemical post-synthetic modification

Mechanochemical grinding of polycrystalline powders of the Prussian blue analogue (PBA) Mn[Co(CN)6]2/3□1/3·xH2O and K3Co(CN)6 consumes the latter and chemically modifies the former. A combination of inductively-coupled plasma and X-ray powder diffraction measurements suggests the hexacyanometallate...

Full description

Bibliographic Details
Main Authors: Cattermull, J, Wheeler, S, Hurlbutt, K, Pasta, M, Goodwin, AL
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2020