Filling vacancies in a Prussian blue analogue using mechanochemical post-synthetic modification

Filling vacancies in a Prussian blue analogue using mechanochemical post-synthetic modification

Mechanochemical grinding of polycrystalline powders of the Prussian blue analogue (PBA) Mn[Co(CN)6]2/3□1/3·xH2O and K3Co(CN)6 consumes the latter and chemically modifies the former. A combination of inductively-coupled plasma and X-ray powder diffraction measurements suggests the hexacyanometallate...

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Dettagli Bibliografici
Autori principali:	Cattermull, J, Wheeler, S, Hurlbutt, K, Pasta, M, Goodwin, AL
Natura:	Journal article
Lingua:	English
Pubblicazione:	Royal Society of Chemistry 2020

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