Dynamics of paramagnetic metallofullerenes in carbon nanotube peapods.

We filled SWNTs with the paramagnetic fullerene Sc@C82 to form peapods. The interfullerene 1D packing distance measured using TEM is d = 1.1 +/- 0.02 nm. The Sc@C82 in SWNT peapods continuously rotated during the 2 s TEM exposure time, and we did not see the Sc atoms. However, Sc@C82 metallofulleren...

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Main Authors: Warner, J, Watt, A, Ge, L, Porfyrakis, K, Akachi, T, Okimoto, H, Ito, Y, Ardavan, A, Montanari, B, Jefferson, J, Harrison, N, Shinohara, H, Briggs, G
格式: Journal article
語言:English
出版: 2008