On the redox reactivity of a geometrically constrained phosphorus(III) compound

The reactivity of a geometrically constrained phosphorus(III) complex bearing the N,N-bis(3,5-di-tert-butyl-2-phenolate)amide pincer ligand towards oxidants and reductants is explored. This compound can be readily oxidized to the phosphorus(V) dihalo-derivatives P(ONO)X2 (X = Cl (2), Br (3) and I (4...

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Bibliographic Details
Main Authors: Robinson, T, De Rosa, D, Aldridge, S, Goicoechea, J
Format: Journal article
Language:English
Published: Wiley 2017