Solid state H-2 NMR study of the orientation and dynamics of cobaltocenium intercalated in the layered silicate LaponiteRD

Ion-exchange intercalation of [Co (η-C5D5)2]+ ions in the smectite clay LaponiteRD [Na0.46Mg5.42Li0'.46Si8(OH)4O20] yields [Mg5.42Li0.46Si8(OH)4O20{Co(η-C5D5)2}0.4Na(0.1)]. Structural and dynamic information about the material was obtained with the benefit of 2H NMR spectroscopic measurements,...

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Bibliographic Details
Main Authors: O'Brien, S, Tudor, J, O'Hare, D
Format: Journal article
Language:English
Published: 1999