Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.
[reaction: see text]. Beta-thioacetal-substituted aldehydes, which are conveniently prepared from the corresponding ynals, can be combined with a range of alkynes or electron-poor alkenes to deliver intermolecular hydroacylation adducts. The reactions employ [Rh(dppe)]ClO4 as a catalyst and are prop...
Автори: | Willis, M, Randell-Sly, H, Woodward, R, Currie, G |
---|---|
Формат: | Journal article |
Мова: | English |
Опубліковано: |
2005
|
Схожі ресурси
Схожі ресурси
-
Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
за авторством: Willis, M, та інші
Опубліковано: (2006) -
Intermolecular alkene and alkyne hydroacylation with beta-S-substituted aldehydes: mechanistic insight into the role of a hemilabile P-O-P ligand.
за авторством: Moxham, G, та інші
Опубліковано: (2008) -
A second-generation catalyst for intermolecular hydroacylation of alkenes and alkynes using beta-S-substituted aldehydes: the role of a hemilabile P-O-P ligand.
за авторством: Moxham, G, та інші
Опубліковано: (2006) -
Traceless chelation-controlled rhodium-catalyzed intermolecular alkene and alkyne hydroacylation.
за авторством: Hooper, J, та інші
Опубліковано: (2013) -
Chelation-controlled intermolecular hydroacylation: direct addition of alkyl aldehydes to functionalized alkenes.
за авторством: Willis, M, та інші
Опубліковано: (2004)