Chelation-controlled intermolecular alkene and alkyne hydroacylation: the utility of beta-thioacetal aldehydes.

[reaction: see text]. Beta-thioacetal-substituted aldehydes, which are conveniently prepared from the corresponding ynals, can be combined with a range of alkynes or electron-poor alkenes to deliver intermolecular hydroacylation adducts. The reactions employ [Rh(dppe)]ClO4 as a catalyst and are prop...

全面介绍

书目详细资料
Main Authors: Willis, M, Randell-Sly, H, Woodward, R, Currie, G
格式: Journal article
语言:English
出版: 2005