Heteroatomic deltahedral clusters: synthesis and structures of closo-[Bi3Ni(4)(CO)6]3-, closo-[Bi4Ni4(CO)6]2-, the open cluster [Bi3Ni6(CO)9]3-, and the intermetalloid closo-[Nix@[Bi6Ni6(CO)8)]4-.

Heteroatomic deltahedral clusters: synthesis and structures of closo-[Bi3Ni(4)(CO)6]3-, closo-[Bi4Ni4(CO)6]2-, the open cluster [Bi3Ni6(CO)9]3-, and the intermetalloid closo-[Nix@[Bi6Ni6(CO)8)]4-.

Reactions of ethylenediamine solutions of K4Bi5 with Ni(PPh3)2(CO)2 yielded four novel hetero-atomic Bi/Ni deltahedral clusters. Three of them, the 7-atom pentagonal bipyramidal [Bi3Ni4(CO)6]3-, the 8-atom dodecahedral [Bi4Ni4(CO)6]2-, and the Ni-centered or empty 12-atom icosahedral [Nix@[Bi6Ni6(CO...

Полное описание

Библиографические подробности
Главные авторы:	Goicoechea, J, Hull, M, Sevov, S
Формат:	Journal article
Язык:	English
Опубликовано:	2007

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