Thin-layer vs. semi-infinite diffusion in cylindrical pores: A basis for delineating Fickian transport to identify nano-confinement effects in voltammetry
Using simulation, voltammetry within a partially electroactive cylindrical pore is investigated. The system studied consists of an insulating cylindrical tube with a ring electrode within its inner circumference, which is filled with electroactive solution, such that electron transfer occurs on the...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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