Thin-layer vs. semi-infinite diffusion in cylindrical pores: A basis for delineating Fickian transport to identify nano-confinement effects in voltammetry

Using simulation, voltammetry within a partially electroactive cylindrical pore is investigated. The system studied consists of an insulating cylindrical tube with a ring electrode within its inner circumference, which is filled with electroactive solution, such that electron transfer occurs on the...

Повний опис

Бібліографічні деталі
Автори: Ward, K, Xiong, L, Lawrence, N, Hartshorne, R, Compton, R
Формат: Journal article
Мова:English
Опубліковано: 2013