Silatropic carbonyl ene cyclizations in the synthesis of pseudosugars and hydroxylated piperidines.
[reaction: see text] We describe two applications of silicon-tethered thermal allyl transfer reactions of alpha-silyloxyaldehydes; formally, these processes can be regarded as silatropic carbonyl ene reactions in which the silicon tether is transferred to the aldehyde oxygen concurrent with carbonyl...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2005
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