Platinum-catalyzed substitution of allylic fluorides

Allyl fluorides are reactive toward Pt-catalyzed alkylation with malonate and likewise toward N- and O-nucleophiles under mild conditions. The reactivity of fluoride as a leaving group equals or exceeds that of the esters and carbonates commonly employed in allylic alkylation. The order of leaving-g...

Descrición completa

Detalles Bibliográficos
Main Authors: Benedetto, E, Keita, M, Tredwell, M, Hollingworth, C, Brown, J, Gouverneur, V
Formato: Journal article
Idioma:English
Publicado: 2012