Platinum-catalyzed substitution of allylic fluorides
Allyl fluorides are reactive toward Pt-catalyzed alkylation with malonate and likewise toward N- and O-nucleophiles under mild conditions. The reactivity of fluoride as a leaving group equals or exceeds that of the esters and carbonates commonly employed in allylic alkylation. The order of leaving-g...
Main Authors: | , , , , , |
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Format: | Journal article |
Sprog: | English |
Udgivet: |
2012
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