Platinum-catalyzed substitution of allylic fluorides

Allyl fluorides are reactive toward Pt-catalyzed alkylation with malonate and likewise toward N- and O-nucleophiles under mild conditions. The reactivity of fluoride as a leaving group equals or exceeds that of the esters and carbonates commonly employed in allylic alkylation. The order of leaving-g...

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Main Authors: Benedetto, E, Keita, M, Tredwell, M, Hollingworth, C, Brown, J, Gouverneur, V
格式: Journal article
语言:English
出版: 2012